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It goes to a syrupy but I don't know why?
It doesn't freeze due to the high alcohol content - alcohol's freezing point is much colder than domestic freezers can get.
Not all vodka's should be served from the freezer though. It can reduce the flavour in some flavoured vodka's - although you could try this if you WANT to reduce the strength of the spirit.
It's 40% alcohol, and alcohol doesn't freeze until -114 oC.
A freezer will only be at about -18 oC.
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